ورقة بحثية
Synthesis and spectroscopic properties of a fluorosensor for Zn2+ ions = التركيب والخصائص الضوئية لحساس طيفي لأيونات الزنك

Al Rasbi, Nawal K.


 

Synthesis and spectroscopic properties of a fluorosensor for Zn2+ ions = التركيب والخصائص الضوئية لحساس طيفي لأيونات الزنك

Al Rasbi, Nawal K.

The new Schiff base ligand L: (E)-N'-(pyridin-2-ylmethylene)acetohydrazide, was synthesized, and its reaction with Zn(II) ions form the complex: [ZnL2](ClO4)2, as confirmed by X-ray crystallography. This complex is stable in polar and non-polar solvents as proven by NMR. A significant enhancement in the fluorescence was observed from L upon coordination to Zn(II) ions over other transition metals such as Fe(II), Co(II), Ni(II), Cu(II), Cd(II) and Ag(I). These results suggest that L can be used as a selective flourosensor for the detection of Zn(II) ions.

The new Schiff base ligand L: (E)-N'-(pyridin-2-ylmethylene)acetohydrazide, was synthesized, and its reaction with Zn(II) ions form the complex: [ZnL2](ClO4)2, as confirmed by X-ray crystallography. This complex is stable in polar and non-polar solvents as proven by NMR. A significant enhancement in...

مادة فرعية

المؤلف : Al Rasbi, Nawal K.

مؤلف مشارك : AlWihibi, Bushra
AlNofali, Nada

بيانات النشر : Muscat، Sultanate of Oman : Sultan Qaboos Journal of Science، 2014مـ.

التصنيف الموضوعي : العلوم البحتة| .

المواضيع : Chemistry .

Zinc .

الكيمياء .

الزنك .

رقم الطبعة : 1

المصدر : Sultan Qaboos University : Muscat، Sultanate of Oman.

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